Determining Crystallite Size Using Scherrer Formula, Williamson-Hull Plot, and Particle Size with SEM
Abstract
It has been determined the crystallite size by XRD technique using Scherrer equation and Williamson-Hull Plot method. While the particle size is determined by SEM using Image-J software. For this purpose, synthesized samples of compound Gd0,95La0.05Ba2Cu3O7-d phase. From the calculation results, obtained the crystallite size in nanometers order, however the crystallite size resulting from the Scherrer equations and Scherrer Modified is different, i.e. 63.1675 nm and 67.0005 nm. The results of the crystallite size calculation by the scherrer equation directly and modified differed from that of the Williamson-Hull Plot method (97,3040 nm). Meanwhile, the results of the Williamson-Hull Plot methods and SEM show almost the same value (98.7297nm).
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References
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http://prism.mit.edu/XRAY/oldsite/CrystalSizeAnalysis.pdf
[5] V. S. Vinila, Reenu Jacob, Anusha Mony, Harikrishnan G. Nair, Sheelakumari Issac, Sam Rajan, Anitha S. Nair, D. J. Satheesh1, Jayakumari Isac, Ceramic Nanocrystalline Superconductor Gadolinium Barium Copper Oxide (GdBaCuO) at Different Treating Temperatures, Journal of Crystallization Process and Technology, vol. 4, 2014, pp. 168-176. http://dx.doi.org/10.4236/jcpt.2014.43021
[6] S. Dinilchenko, O. Kukharenko, C. Moseke, I. Protsenko, L. Sukhodub and B. Sulkio-Cleff, “Determine Bone Mineral Crystallite Size and Lattice Strain from Diffraction Line Broadening,” Research and Technology Crystal, vol. 37, no. 11, 2002, pp. 1234-1240.
[7] S. Gencalp Irizalp, N. Saklakoglu, Laser Peening of Metallic Materials, Reference Module in Materials Science and Materials Engineering Comprehensive Materials Finishing, vol. 1, 2017, pp. 408–440.
https://doi.org/10.1016/B978-0-12-803581-8.09160-8.
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http://www.scirp.org/journal/msce
[9] Ahmad Monshi, Mohammad Reza Foroughi, Mohammad Reza Monshi, Modified Scherrer Equation to Estimate More Accurately Nano-Crystallite Size Using XRD, World Journal of Nano Science and Engineering, vol. 2, 2012, pp. 154 - 160.
http://dx.doi.org/10.4236/wjnse.2012.23020.
[10] Qing Li, Christina W. Kartikowati, Shinji Horie, Takashi Ogi, Toru Iwaki & Kikuo Okuyama, Correlation between particle size/domain structure and magnetic properties of highly crystalline Fe3O4 nanoparticles, Scientific Reports, vol. 7: 9894, 2017, pp.– 7. http://dx.doi.org/10.1038/s41598-017-09897-5.
[11] Douglas A. Skoog, James J. Leary, Principles of Instrumentatl Analysis, 4th edition, Sounders College Publisher, New York, 1992, pp. 985.
Published
2018-07-01
How to Cite
SUMADIYASA, Made; MANUABA, I.B.S..
Determining Crystallite Size Using Scherrer Formula, Williamson-Hull Plot, and Particle Size with SEM.
BULETIN FISIKA, [S.l.], v. 19, n. 1, p. 28 - 34, july 2018.
ISSN 2580-9733.
Available at: <https://ojs.unud.ac.id/index.php/buletinfisika/article/view/39344>. Date accessed: 22 nov. 2024.
Section
Articles
