The Conductance and Swelling of Composite Membrane ‘Chitosan-Silver Nanoparticles’ in Monovalent Salt Solution ‘KCl and NaCl’
Abstract
A research about to determine the conductance and water absorption capacity (swelling) of the composite membrane has been conducted. The membrane used was a membrane made of chitosan matrix, silver nanoparticle(AgNP) of 100 µg as a filler and acetic acid 1% as a solvent, which named chitosan composite membrane (Ch-AgNP). A 2% chitosan membrane (membrane Ch) used as a comparison. The membrane conductance value determined by measuring the membrane voltage (V) as a function of current (I) in monovalent salt solutions of NaCl and KCl with a concentration of 0.025 M. The swelling tests have been carried out using distilled water. The results showed that Ch membrane conductance was greater than the Ch-AgNP composite membrane. In KCl solution, the conductance is 0.0991 ?-1 and 0.0984 ?-1 and in NaCl solution are 0.1002 ?-1 and 0.0996 ?-1. The membrane conductance is greater in NaCl solution than in KCl solution. The swelling test showed that the swelling percentage of Ch-AgNP composite membrane was greater than Ch membrane
Downloads
References
[2] D. Yanming, X. U. Congyi, et al., Determination of Degree of Substitution For N-Acylated Chitosan Using IR Spectra, Science in Chine, vol. 44, no. 2, 2001, pp. 216-224.
[3] S. Aprilia, Pembuatan Membran Komposit Khitosan-Selulosa dari Limbah Kulit Kepala Udang, Jurnal Rekayasa dan Lingkungan, vol. 5, no. 1, Universitas Syiah Kuala, Aceh, 2006, halaman 28-35.
[4] W. Ariyanto, Pembuatan Membran Komposit Kitosan-Vanilin/Polivinil Alcohol/Lempung Sebagai Membran Elektrolit, Skripsi, Universitas Sebelas Maret, Surakarta, 2012.
[5] I. F. Farha dan N. Kusumawati, Pembuatan Membran Komposit Kitosan-PVA dan Pemanfaatannya pada Pemisahan Limbah Pewarna Rhodamin-B, Prosiding Seminar Nasional Kimia, Universitas Negeri Surabaya, Surabaya, 2012.
[6] Meriatna, Penggunaan Membran Kitosan untuk Menurunkan Kadar Logam Krom (Cr) Dan Nikel (Ni) dalam Limbah Cair Industri Pelapisan Logam, Tesis, Universitas Sumatera Utara, Medan, 2008.
[7] I. Ristian, Kajian Pengaruh Konsentrasi Perak Nitrat (AgNO3) Terhadap Ukuran Nanopartikel Perak, Skripsi, Universitas Semarang, Semarang, 2013.
[8] J. H. Choi, H. Joo and S. H. Moon, Effect of Electrolytes on the Transport Phenomena in a Cation-Exchange Membrane, Journal of Collid and Interface Science, vol. 238, 2001, pp.188-195.
[9] N. M. Rasmini, Pengaruh Jenis Larutan Elektrolit Terhadap Karakteristik Arus-Tegangan Membran Kitosan, Skripsi, Jurusan Fisika FMIPA Universitas Udayana, Bali, 2016.
[10] C. M. Liberman and J. Adams, Ions, Channels, Current and Electrical Potentials, HST 721 The Peripheral Auditory System, Harvard-MIT Division of Health Science and Technology, 2005.
[11] N. N. Rupiasih, Effects of electrolytes on ion transport in Chitosan membranes, Journal of Physics: Conference Series, vol. 776, no. 1, 2016, 012045(1-6).
[12] A. A. Zoucella, Sintesis dan Karakterisasi Sifat-sifat Fisik Membran Komposit Kitosan-Nanopartikel Perak, Skripsi, Jurusan Fisika FMIPA Universitas Udayana, Bali, 2017.