The Study of Current-Voltage (I-V) Characteristic Curve of Chitosan-Silver Nanoparticle Composite Membrane

  • Maulida Nirwana Islami Universitas Udayana
  • Ni Nyoman Rupiasih Udayana University
  • Made Sumadiyasa Udayana University
  • I B Sujana Manuaba Udayana University

Abstract

A study of the current-voltage (I-V) curve of the chitosan-silver nanoparticle composite membrane (Ch-AgNP) has been conducted. Membranes were prepared by casting method using chitosan as matrix, acetic acid 1% as solvent and silver nanoparticle (AgNP) as filler. AgNP used was 100 ?g. As a comparison is a pure chitosan membrane (membrane Ch). The I-V measurement was performed using a cell model consisting of 2 chambers, chambers 1 and 2. The voltage (V) was measured using Ag/AgCl calomel electrode in electrolyte solution of KCl and CaCl2 with concentration of 0.025 M. All measurements were done at room temperature ± 28 0C. The result shows that in the current range 0.66-0.98 mA, the I-V curve of the Ch-AgNP membrane is ohmic. The conduction value of the composite membrane is smaller than that of the chitosan membrane and the value is greater in the KCl solution than in CaCl2 solution.


 

Downloads

Download data is not yet available.

References

[1] Pratomo, H., Pembuatan dan Karakterisasi Membran Komposit Polisulfon Selulosa Asetat untuk Proses Ultrafisasi, Jurnal Pendidikan Matematika dan Sains, Edisi 3 Tahun VIII, Jurusan Pendidikan Kimia FMIPA UNY, Yogyakarta, 2003.
[2] N. N. Rupiasih, Effects of electrolytes on ion transport in Chitosan membranes, Journal of Physics: Conference Series, vol. 776, no. 1, 2016, 012045(1-6).
[3] W. Siti, S. Suyanto, Y. Yuliana, Pembuatan Dan Karakterisasi Membran Komposit Kitosan-Sodium Alginat Terfosforilasi Sebagai Proton Exchange Membrane Fuel Cell (PEMFC), Journal Kimia Riset, vol. 1, no. 1, Juni 2016, pp. 14-21.
[4] Meriatna, Penggunaan Membran Kitosan untuk Menurunkan Kadar Logam Krom (Cr) Dan Nikel (Ni) dalam Limbah Cair Industri Pelapisan Logam, Tesis, Universitas Sumatera Utara, Medan, 2008.
[5] M. Soleiman, M. Ghorbani and S. Salahi, Antibacterial Activity of Polypyrrole-Chitosan Nanocomposite: Mechanism of Action, International Journal of Nanoscience and Nanotechnology, vol. 12, no. 3, September 2016, pp. 191-197.
[6] A. W. Diah, A. Lukman, Pengaruh Variasi Konsentrasi Metanol terhadap Sifat Permeabilitas Metanol Membran Komposit Kitosan/Monmorillonit Termodifikasi Silan 10%, Jurnal Sains Dan Seni ITS, vol. 5, no. 2, 2016, pp. 97-102.
[7] K. M. Dina, H. Rusly, Preparasi Dan Karakterisasi Komposit Kitosan-ZnO/ Al2O3, Molekul, vol. 10, no. 1, Mei 2015, pp. 9-18.
[8] Erizal, A. Basril, W. Yessy, Darmawan, Sintesis Dan Karakterisasi Membran Komposit Kitosan-Hidroksi Apatit Berikatan Silang Sebagai Guided Tissue Regeneration (GTR), Majalah Metalurgi, vol. 28, no.1, 2013, pp. 55-64.
[9] S. Dorlina, A. Henry, S. K. Vanda, Sintesis Nanopartikel Perak (Ag) Dengan Reduktor Natrium Borohidrida (NaBH4) Menggunakan Matriks Nata-De-Coco, Chem. Prog., vol. 9, no. 2, November 2016, pp. 40-47.
[10] F. Azizah, Kajian Sifat Listrik Membran Selulosa Asetat yang Direndam dalam Larutan Asam Klorida dan Kalium Hidroksida, Skripsi, Departemen Fisika FMIPA Institut Pertanian Bogor, Bogor, 2008.
[11] J. H. Choi, H. Joo and S. H. Moon, Effect of Electrolytes on the Transport Phenomena in a Cation-Exchange Membrane, Journal of Collid and Interface Science, vol. 238, 2001, pp.188-195.
[12] A. A. Zoucella, Sintesis dan Karakterisasi Sifat-sifat Fisik Membran Komposit Kitosan-Nanopartikel Perak, Skripsi, Jurusan Fisika FMIPA Universitas Udayana, Bali, 2017.
Published
2018-08-01
How to Cite
ISLAMI, Maulida Nirwana et al. The Study of Current-Voltage (I-V) Characteristic Curve of Chitosan-Silver Nanoparticle Composite Membrane. BULETIN FISIKA, [S.l.], v. 19, n. 2, p. 40-45, aug. 2018. ISSN 2580-9733. Available at: <https://ojs.unud.ac.id/index.php/buletinfisika/article/view/38402>. Date accessed: 25 apr. 2024.

Most read articles by the same author(s)

1 2 3 4 5 > >>