DEGRADASI FOTOKATALITIK LIMBAH CAIR BATIK JAMBI MENGGUNAKAN KATALIS HETEROGEN CAO DARI CANGKANG KERANG BAMBU (ENSIS SP.)

  • A. Saputra Program Studi Kimia, Fakultas Sains dan Teknologi, Universitas Islam Negeri Sulthan Thaha Saifuddin Jambi, Jambi, Indonesia
  • W. Utami Program Studi Kimia, Fakultas Sains dan Teknologi Universitas Islam Negeri Sulthan Thaha Saifuddin Jambi, Jambi, Indonesia http://orcid.org/0000-0002-1906-3613
  • S. Ningsih Program Studi Kimia, Fakultas Sains dan Teknologi, Universitas Islam Negeri Sulthan Thaha Saifuddin Jambi, Jambi, Indonesia
  • Deliza . Program Studi Kimia, Fakultas Sains dan Teknologi, Universitas Islam Negeri Sulthan Thaha Saifuddin Jambi, Jambi, Indonesia http://orcid.org/0000-0003-0320-1345

Abstract

           Limbah cair zat warna Batik Jambi mengandung senyawa organic non-biodegradable yang bersifat karsinogenik. Tujuan penelitian ini untuk mengetahui efektivitas katalis CaO dalam mendegradasi limbah cair zat warna Batik Jambi. Pada penelitian ini, limbah cair zat warna Batik Jambi didegradasi menggunakan metode fotokatalitik  penyinaran matahari dan lampu UV 38 watt dengan dan tanpa katalis CaO dari cangkang kerang bambu. Larutan limbah warna dianalisis menggunakan spektrofotometer UV-VIS pada panjang gelombang 200-800 nm dengan massa katalis 0,02 gram. Data memperlihatkan bahwa hasil degradasi limbah cair zat warna Batik Jambi yang paling baik yaitu penambahan katalis CaO dan penyinaran matahari selama 3 jam sebesar 60,34%. Sedangkan penyinaran lampu UV selama 3 jam hanya sebesar 36,12%. Hasil penelitian dapat memberikan beberapa manfaat yaitu sebagai sumber informasi bagi pengrajin batik tentang pengolahan limbah cair Batik secara sederhana. Selain itu, studi ini sebagai data dukung bagi pemerintah tentang pembuatan produk hukum terkait pengolahan limbah cair batik yang belum terperhatikan.


Kata kunci: Batik Jambi, CaO, degradasi, fotokatalitik, katalis


ABSTRACT


           The wastewater of Batik Jambi dye contains non-biodegradable organic compounds that are carcinogenic. The purpose of this study was to determine the effectiveness of the CaO catalyst in degrading the Batik Jambi dye wastewater. In this research, Batik Jambi dye wastewater was degraded using the photocatalytic method the solar irradiation and a 38-watt UV lamp with and without a CaO catalyst from bamboo shells. The colored waste solution was analyzed using a UV-VIS spectrophotometer at a wavelength of 200-800 nm with a catalyst mass of 0.02 grams.  The data showed that the best result of degradation of Jambi Batik dye wastewater was the addition of a CaO catalyst and solar irradiation for 3 hours of 60.34%. Whereas UV light irradiation for 3 hours was only 36.12%. The result of research could provide several benefits, namely as a source of information for batik craftsmen about the simple processing of liquid waste. In addition, this study served as supporting data for the government regarding the manufacture of law product related to the treatment of batik wastewater which has not been considered


Keywords: catalyst, CaO, degradation, photocatalytic

Downloads

Download data is not yet available.

References

Alsohaimi, I. H., Nassar, A. M. Elnasr, T. A. S., Cheba, B. A. 2020. A novel composite silver nanoparticles loaded calcium oxide stemming from egg shell recycling : A potent photocatalytic and antibacterial activities. Journal of Cleaner Production. 248. 119274.
Beyan, S. M., Prabhu, S. V., Sissay, T.T., Getahun, A.A. 2021. Sugarcane bagasse based activated carbon preparation and its adsorption efficacy on removal of BOD and COD from textile effluents : RSM based modeling , optimization and kinetic aspects. Bioresource Technology Reports. 14. 1-9.
Deliza. 2014. Degradasi Senyawa Zat Warna Rhodamin B Secara Fotokatalis Dengan Penambahan Katalis Heterogen TiO2-NiFe2O4, TiO2-CuFe2O4, dan TiO2-MnFe2O4. Skripsi. Departemen Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam. Universitas Andalas.
Deliza. 2016. Degradasi Zat Warna Direct Red-81 dan Direct Yellow-27 Melalui Proses Ozonolisis, Fotolisis dengan Sinar UV Dan Cahaya Matahari Menggunakan Katalis N-Doped TiO2 dan C-N-Codoped TiO2. Tesis. Departemen Kimia, Fakultas Matematika dan Ilmu Pengetahuan Alam. Universitas Andalas.
Deliza, D., Syukri, A., Wulanda, M. N., Sartika, D. 2021. Detection of metal elements within Inductively Couple Plasma Emission Jambi batik waste and views as Muslim education. In Journal of Physics: Conference Series. 1869(1). 012059.
Eskikaya, O. Gun, M., Bouchareb, R., Bilici, Z., Dizge, N., Ramaraj, R., Balakrishnan, D. 2022. Photocatalytic activity of calcined chicken eggshells for Safranin and Reactive Red 180 decolorization. Chemosphere. 304. 135210.
Girsang, N. D. 2021. Literature study of convolutional neural network algorithm for batik classification. Brilliance Research of Artificial Intelligence. 1(1). 1–7.
Hachoumi, I., Ouahabi, I. E., Slimani, R., Cagnon, B., Haddad, M.E. Antri, S. E., Lazar, S. 2017. Adsorption studies with a new biosorbent ensis siliqua shell powder for removal two textile dyes from aqueous solution. Journal of Material and Environmental Science. 8(4). 1448–1459.
Harichandran, G., Prasad, S. 2016. SonoFenton degradation of an azo dye, Direct Red. Ultrasonics sonochemistry. 29. 178–185.
Jaiswal, K. K. Dutta, S., Pohrmen, C. B., Verma, R., Kumar, A., Ramaswamy, A.P. 2020. Bio-waste chicken eggshell-derived calcium oxide for photocatalytic application in methylene blue dye degradation under natural sunlight irradiation. Inorganic and Nano-Metal Chemistry. 51(7). 995-1004.
Mahila, S. 2018. Keberadaan Hak Kekayaan Intelektual Seni Batik Jambi di Kota Jambi. Jurnal Ilmiah Universitas Batanghari Jambi. 18(3). 565–574.
Meshko, V., Markovska, L., Micheva, M., Rodrigues, A.E. 2001. Adsorption of basic dyes on granular acivated carbon and natural zeolite. Water Research. 35(14). 3357–3366.
Milea, F. 2021. The social constructivism of entreprenurial process in smes revitalization : a case of batik industry in Indonesia. Academy of Entrepreneurship Journal. 27(4).1-11.
Muryati, M., Hariani, P. L., Said, M. 2019. Preparation and characterization nanoparticle calcium oxide from snakehead fish bone using ball milling method. Indonesian Journal of Fundamental and Applied Chemistry. 4(3). 111–115.
Nguyen, D. K., On, V., Rivas-Silva, .F., Cocoletzi, G. H. 2021. Structural, electronic, magnetic and optical properties of CaO induced by oxygen incorporation effects: A first-principles study. Physics Letters A. 397. 127241.
Naimah, S., A. Ardhanie, S., Jati, B.N., Aidha, N. N., C. Arianita, A. 2014. Degradasi Zat Warna Pada Limbah Cair Industri Tekstil Dengan Metode Fotokatalitik Menggunakan Nanokomposit TiO2 – Zeolit. Jurnal Kimia Kemasan. 36. 25-236.
Nawawi, M. T., Rodhiah, R. 2020. SWOT analysis on the smes of batik products in jambi city. Atlantis Press. 145. 356–360.
Kusumaningrum, D. I. P., Sudarni, D. H. A., Wahyuningsih, S. 2022. Optimasi Pengaruh Waktu Kontak dan Dosis Adsorben Limbah Daun Kayu Putih (Melaleuca cajuputi) dengan Metode Isoterm Adsorpsi Langmuir. Jurnal Teknik Kimia USU, 11(2), 72-79.
Putri, W., Rahmah, A., Mayasari, R., Nurmita, N., Deliza, D., Utami, W., Tanti, D., Ma’ruf, R. 2022. Is Batik Bad for Water and The Environment? Reveal The Perception of Batik Craftsmen About Environmental Care. In Proceedings of the 4th International Colloquium on Interdisciplinary Islamic Studies in conjunction with the 1st International Conference on Education, Science, Technology, Indonesian and Islamic Studies, ICIIS and ICESTIIS 2021, 20-21 October 2021, Jambi, Indonesia.
Rachmawati, V., Nurjayati, R., Yuniati, M. D. 2022. Penurunan Konsentrasi COD Limbah Batik Pada Proses Seeding dan Aklimatisasi Menggunakan Material Preservasi Mikroorganisme (MPMO). Jurnal Kesehatan Lingkungan Indonesia. 21(1). 73-82.
Sanjani, A., Oktaviana, D., & Ningtyas, N. S. I. 2022. Identifikasi kandungan tannin dan saponin hijauan pakan sapi potong di desa senayan kabupaten sumbawa baraT. Jurnal Sangkareang Mataram. 9(2). 28-33.
Sela, S. K., Nayab-Ul-Hossain, A. K. M., Hussain, S. Z., Hasan, N. 2020. Utilization of prawn to reduce the value of BOD and COD of textile wastewater. Cleaner Engineering and Technology. 1. 100021.
Solanki, V. S., Pare, B., Gupta, P., Jonnalagadda, S. B., Shrivastava, R. 2020. A Review on Advanced Oxidation Processes (AOPs) for Wastewater Remediation. Asian J. Chem. 32. 2677-2684.
Thakur, S., Singh, S., Pal, B. 2022. Superior adsorptive removal of brilliant green and phenol red dyes mixture by CaO nanoparticles extracted from egg shells. Journal of Nanostructure in Chemistry. 12(2). 207-221.
Tian, W., Chen, G., Gui, Y., Zhang, G., Li, Y. 2021. Rapid quantification of total phenolics and ferulic acid in whole wheat using UV–Vis spectrophotometry. Food Control. 123. 107691.
Utami, W. 2022. Synthesize and characterization of heterogeneous catalyst: ensis sp. shell waste. Jurnal Inovasi Pendidikan dan Sains. 3(3). 137-142.
Van Hung, N., Nguyet, B. T. M., Nghi, N. H., Khieu, D. Q. 2021. Photocatalytic degradation of methylene blue by using ZnO/longan seed activated carbon under visible-light region. Journal of Inorganic and Organometallic Polymers and Materials, 31, 446-459.
Wellia, D. V., Takeuchi, T. 2019. Photocatalytic degradation of Direct Yellow-27 by photolysis with UV-light and solar irradiation Using N-doped TiO2. KnE Engineering. 62-74.
Published
2023-07-31
How to Cite
SAPUTRA, A. et al. DEGRADASI FOTOKATALITIK LIMBAH CAIR BATIK JAMBI MENGGUNAKAN KATALIS HETEROGEN CAO DARI CANGKANG KERANG BAMBU (ENSIS SP.). Jurnal Kimia (Journal of Chemistry), [S.l.], p. 151-157, july 2023. ISSN 2599-2740. Available at: <https://ojs.unud.ac.id/index.php/jchem/article/view/99065>. Date accessed: 21 nov. 2024. doi: https://doi.org/10.24843/JCHEM.2023.v17.i02.p06.
Section
Articles