PEMANFAATAN KITOSAN DALAM PENINGKATAN MUTU NIRA GULA TEBU

  • Moh. Hamzah Pusat Teknologi Material – TIEM, BPP Teknologi Kawasan Puspiptek Serpong, Tangerang Selatan, Banten, Indonesia
  • Mahendra Anggaravidya Pusat Teknologi Material – TIEM, BPP Teknologi Kawasan Puspiptek Serpong, Tangerang Selatan, Banten, Indonesia
  • Ika Maria Ulfa Pusat Teknologi Material – TIEM, BPP Teknologi Kawasan Puspiptek Serpong, Tangerang Selatan, Banten, Indonesia
  • Rina Dewi Mayasari Pusat Teknologi Material – TIEM, BPP Teknologi Kawasan Puspiptek Serpong, Tangerang Selatan, Banten, Indonesia
  • Sudirman Habibie Pusat Teknologi Material – TIEM, BPP Teknologi Kawasan Puspiptek Serpong, Tangerang Selatan, Banten, Indonesia
  • Dwi Astuti Pusat Teknologi Material – TIEM, BPP Teknologi Kawasan Puspiptek Serpong, Tangerang Selatan, Banten, Indonesia

Abstract

ABSTRAK : Gula kristal putih (GKP) merupakan bahan pemanis alami dari bahan baku sebagai sumber kalori dan energi. Kebutuhan GKP nasional yang semakin tinggi akibat pertambahan populasi penduduk tidak diimbangi dengan tingkat produksi industri gula yang mencukupi. Permasalahan industri gula nasional saat ini disebabkan oleh rendahnya kualitas rendemen, kondisi mesin dan pabrik yang sudah tua, dan teknologi atau metodologi yang tidak berkembang. Untuk mendukung peningkatan produktivitas dan mutu gula nasional maka perlu dilakukan inovasi teknologi dengan memanfaatkan kitosan (chitosan) yang ramah lingkungan. Keunggulan teknis kitosan antara lain: pengikat ion logam, decolorization, dan flokulan yang dapat meningkatkan mutu gula. Penelitian ini telah berhasil melakukan pemurnian nira gula dengan menggunakan kitosan berpelarut 3 jenis asam organik, yaitu asam oksalat, asam sitrat, dan asam asetat. Berdasarkan hasil analisis kekeruhan nilai NTU nira tebu setelah dilakukan pemurnian dengan kitosan berpelarut 3 jenis asam organik turun hingga 88%-95% terhadap bahan baku nira gula (referensi). Kadar kalium (K) dan magnesium (Mg) pada nira hasil pemurnian juga turun hingga 46%-87% dan 24%-40%, secara berturut-turut. Dari ketiga jenis asam organik pelarut kitosan, asam oksalat memiliki potensi untuk dikembangkan hingga skala industri pada proses pemurnian nira gula karena memiliki nilai NTU terkecil sebesar 41,6; kadar K 1,67 mg/L; dan kadar  Mg 7,03 mg/L.


 


ABSTRACT: White crystal sugar is a natural sweetener which can be an alternativecalorie and energy source. The high need of national sugar due to the growthof population does not balanced by the adequate production of sugar industry. The problems of national sugar industries are caused by the low quality of sucrose content, the condition of old machines and factory, and undeveloped either technology or methodology. Technology innovation need to be developed for supporting the enhance of national productivity and sugar quality, such as using chitosan in the sugarcane purification. The chitosan advantages include metal ion binder, decolorization, and flocculants which can improve the quality of sugar. This research has been successfully refined sugarcane using chitosan dissolved in three organic acids, i.e. oxalic acid, citric acid, and acetic acid. Based on the analysis data of turbidity, the NTU value of purified sugarcane using chitosan decreased in 88%-95% due to the raw sugarcane (reference). The kalium (K) and magnesium (Mg) contents of chitosan-purified sugarcane also reduced to 46%-87% and 24%-40%, respectively. From the three organic acids, oxalic acid has a potential to be developed in industrial scale of sugarcane purification because it has the smallest turbidity value of 41.6 NTU, K content of 1,67 mg/L; and Mg content of 7,03 mg/L.

Downloads

Download data is not yet available.

References

[1] Departemen Perindustrian, 2009. Roadmap Industri Gula. Direktorat Jendral Industri Agro dan Kimia, Departemen Perindustrian, Jakarta.
[2] Walfrod, S. N., 1996.Composition of Cane Juice, Sugar milling Research Institute, University of Natal, Durban.
[3] Kearsley, M.W., Dziedzic, S.Z., 1995.Handbook of Starch Hydrolysis Products and Their Derivatives. Chapman Hill, London.
[4] Nick, J.B., 1992. A Review of Physical and Chemical Properties of Char which Affect Its Decolorizing Ability, Proc. 51 Annual Meeting of Sugar Industry Technologists Inc.
[5] Clarke, M. A., R. S. Blanco, and M. A. Godshall, 1984. Color Test and Other Indicators of Raw Sugar Refining Characteristics, Proc. Sugar Processing Research Conference.
[6] Carpenter, 1985.Cane Sugar refining II. Ch 17. In Cane Sugar Handbook. Eleventh Edition Chen, J.C.P (ed). John Wiley & Son, New York.
[7] Smith P. and Gregory P.E., 1971. Sugarcane Technology. Proc. Int. Soc.,pp. 1415-1425.
[8] Kurniawan, Y., 2009. Bachtiar, A., dan Triantarti. Potret Kualitas Gula Kristal Putih dan Upaya Peningkatan Menuju SNI GKP. Prosiding Seminar. Pusat Penelitian Perkebunan Gula Indonesia, p. 5.
[9] Anonim, 2011.Model Pengembangan Kawasan Agribisnis Tebu. Bahan Kajian MK, Metode Pengembangan Wilayah. PMPSLP PPSUB.
[10] Abbara A.A., Abdei-Rahman A.K., Bayoumi M.R.,2007. Application of membrane filtration to the sugar industry, state of the art.
[11] HertzogE. S. and BroderickS. J., 1941. Activated Carbon for Sugar Decolorization. Ind. Eng. Chem.,Vol. 33 (9): 1192–1198.
[12] Pale A.A., 1950.Methode for Purifing Sugar Cane, patent, United States Patent Office.
[13] Stevens, and Rex R.,1991. Process for Decolorizing Aqueous Sugar Solution. European Patent Application. Publication number EP 0 417 361 A1.
[14] Kaseno, Wulyoadi, Sasmito, dan Koesnandar, 2002. Penerapan Teknologi Mernbran pada Pernurnian Nira Tebu pada Pabrik Gula. Jurnal Sains dan Teknologi 7(2a):02.
[15] Chou C.C. and Kwok R.J., 2004. Direct Production of Refined Sugar and Value Added Products from Sugar Cane Mills. Third Annual Technical Conference Vancouver. Canada.
[16] Suprihatin, 2007. Penjernihan Nira Tebu Menggunakan Membran Ultrafiltrasi Dengan Sistem Aliran Silang. Jurnal Ilmu Pertanian Indonesia, 12(2): 93 – 99
[17] Jensen C.R.C., 2007. Direct White Sugar Manufacture in the Cane Sugar Industry Via Membrane Filtration And Continuous Ion-Exchange Demineralization. Zuckerindustrie, 132(6): 446–452.
[18] Yulianingtias H.P., 2010. Peningkatan Efektifitas Pemurnian Nira Tebu Menggunakan Mikrofiltrasi Membran Skala Laboratorium. Skripsi: Jurusan Kimia FMIPA, Universitas Negeri Malang.
[19] Susanto H., Roihatin A., dan Widiasa I.N., 2013. Penghilangan Warna Larutan Gula dengan Membran Ultrafiltrasi. Prosiding Seminar Nasional Teknik Kimia Teknologi Oleo dan Petro Kimia.
[20] Sugita P., Wukirsari T., Sjahriza A., dan Wahyono D., 2009. Kitosan: Sumber Biomaterial Masa Depan. Bogor (ID): Institut Pertanian Bogor Press.
[21] Muzzarelli, RAA. Chitin, and Pergamon, 1977. Oxford, Chapter 6.
[22] Santas J., and Rafecas M, 2010. Saturated Fatty Acid Absorption is Selectively Reduced by Chitosan in Relation to Chain Length, 8th Euro Fed Lipid Congress.
[23] Gamage, D.A.S., 2003.Use of chitosan for the removal of metal ion contaminants and proteins from water, Master thesis. Memorial University of Newfoundland.
[24] Cheng J., Xie, S., Wang S., Xue, Y, Jiang, L., Liu, L., 2016. Optimization of Protein Removal from Soybean Whey Wastewater Using Chitosan Ultrafiltration. Journal of Food Process Engineering, 40(2): 1 – 9
[25] Haryati S. dan Kristiani E.B., 2014. Pengaruh Penambahan Larutan Khitosan Terhadap Kadar Tanin, Vitamin C Dan Kejernihan Pada Sari Buah Jamblang (Eugenia Cumin Merri) Pasca Perlakuan Blanching. Teknologi Pangandan Hasil Pertanian, 7(2): 77 – 88
[26] Mao, L. and Wu, T., 2007. Gelling Properties and Lipid Oxidation of Kamaboko Gels from Grass Carp (Ctenopharyngodonidellus) Influenced by Chitosan. Journal of Food Engineering, 82: 128 – 134
[27] Khor, E. and Lim, L.Y., 2003. Implantable Applications of Chitin and Chitosan. Biomaterials, 24: 2339 -2349
[28] Nurdiani D., 2005. Adsorpsi Logam Cu(II) Dan Cr(VI) Pada Kitosan Bentuk Serpihan Dan Butiran, Skripsi, Institut Pertanian Bogor.
[29] Tutor Vista Company, 2016.http://chemistry.tutorvista.com.
[30] Bhat M.A., Mukhtar F., Chisti H., and Shah S.A., 2014. Removal Of Heavy Metal Ions From Waste Water By Using Oxalic Acid: An Alternative Method, International Journal of Latest Research in Science and Technology, 3(3); 61 – 64
[31] Inoue K., Baba Y. and Yoshizuka K., 1993. Adsorption of metal ions on chitosan and crosslinked copper (II)−complexed chitosan. Bulletin of the Chemical Society of Japan, 66(5); 2915−2921.
[32] Wan Ngah W.S., Isa I.M., 1998. Comparison Study of Copper Ion Adsorption on Chitosan, Journal of Applied Polymer Science, 67(6); 1067 – 1070.
Published
2020-05-31
How to Cite
HAMZAH, Moh. et al. PEMANFAATAN KITOSAN DALAM PENINGKATAN MUTU NIRA GULA TEBU. CAKRA KIMIA (Indonesian E-Journal of Applied Chemistry), [S.l.], v. 8, n. 1, p. 1 - 8, may 2020. ISSN 2302-7274. Available at: <https://ojs.unud.ac.id/index.php/cakra/article/view/62789>. Date accessed: 21 nov. 2024.