OPTIMASI ADSORPSI METILEN BIRU MEMANFAATKAN SABUT BUAH LONTAR TERAKTIVASI ASAM
Abstract
ABSTRAK: Penelitian ini bertujuan untuk memanfaatkan limbah sabut buah lontar sebagai adsorben metilen biru. Sabut buah lontar dihaluskan hingga ukuran 100 mesh kemudian diaktivasi menggunakan asam sulfat 1M selama 24 jam. Biosorben yang dihasilkan kemudian dicuci dengan aquades hingga pH netral. Biosorben digunakan untuk adsorpsi metilen biru dengan parameter uji variasi pH, waktu kontak, dan konsentrasi awal adsorbat. Hasil pengujian menunjukkan bahwa pH optimum 7, waktu kontak 50 menit dan konsentrasi maksimum 50 ppm. Model kinetika adsorpsi adalah pseudo orde dua dengan nilai R2 adalah 1 dan isotermal adsorpsi yang berlaku adalah isotermal Freundlich yang mengindikasikan bahwa proses adsorpsi terjadi secara multilayer. Dari hasil ini dapat disimpulkan bahwa metilen biru dapat diadsorpsi menggunakan sabut buah lontar teraktivasi asam.
ABSTRACT: This research aims to using the lontar fiber as methylene blue adsorbent. The palm fruit fiber was prepared to particle size of 100 mesh then activated using 1M of sulphuric acid for 24 hours. The biosorbent washed with distilled water until the pH was neutral. Biosorbent was used for methylene blue adsorption with parameters tested included pH, contact time and variations in concentration. The test results show that the optimum pH is 7, the contact time is 50 minutes and the maximum concentration is 50 ppm. The adsorption kinetic models following pseudo second order with an R2 value of 1 and the adsorption isothermal is the Freundlich isothermal which indicates that the adsorption process occur in a multilayer manner. From these results it can be concluded that methylene blue can be adsorbed using acid-activated palm fiber.
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References
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doi: 10.1016/j.heliyon.2022.e10868.
[17] A. Talaiekhozani, M. Reza Mosayebi, M. A. Fulazzaky, Z. Eskandari, and R. Sanayee. Combination of TiO2 microreactor and electroflotation for organic pollutant removal from textile dyeing industry wastewater. Alexandria Engineering Journal, 2020, 59(2), 549–563,
doi: 10.1016/j.aej.2020.01.052.
[18] Riyanto and M. Mawazi. Electrochemical Degradation of Methylen Blue Using Carbon Composite Electrode (C-PVC) in Sodium Chloride. IOSR Journal of Applied Chemistry, 2015, 8(11), 31–40
[19] T. E. Banamtuan, A. B. Baunsele, and A. M. Kopon. Studi Adsorpsi Metilen Biru Memanfaatkan Sabut Buah Lontar. Jurnal Inovasi Teknik Kimia, 2023, 8(2), 108-116
doi: 10.31942/inteka.v8i2.8065.
[20] S. T. Nipa, N.R. Shefa, S. Parvin, M. A. Khatun, M. J. Alam., S. Chowdhury, M. A. R., Khan, S. M. A. Z. Shawon, B. K., Biswas., M.W. Rahman. Adsorption of methylene blue on papaya bark fiber: Equilibrium, isotherm and kinetic perspectives. Results in Engineering, 2023, 17, 100857
doi: 10.1016/j.rineng.2022.100857.
[21] A. Ahmad, D, Jini, M. Aravind, C. Parvathiraja, R. Ali, M. Z. Kiyani, A.,Alothman. A novel study on synthesis of egg shell based activated carbon for degradation of methylene blue via photocatalysis. Arabian Journal of Chemistry, 2020, 13(12), 8717–8722,
doi: 10.1016/j.arabjc.2020.10.002.
[22] A. B. Baunsele and H.- Missa. Langmuir and Freundlich Equation Test on Methylene Blue Adsorption by Using Coconut Fiber Biosorbent. Walisongo Journal of Chemistry, 2021, 4(2), 131–138
doi: 10.21580/wjc.v4i2.8941.
[23] H. Febriani, D. J. Puspitasari, Ruslan, and H. Sosidi. Adsorbsi Ion Logam Cu (II) Menggunakan Biomassa Daun Genjer (Limnocharis flava): Adsorption of Cu (II) Ions by Biomass of Genjer Leaves (Limnocharis flava). Kovalen, 2021, 7(2), 131–136,
doi: 10.22487/kovalen.2021.v7.i2.14009.
[24] C. Wulandari, F. H. Sofia, and K. Udyani. Pengolahan Limbah Cair Pembuatan Sarung Tenun Menggunakan Biosorben Tongkol Jagung Teraktivasi HNO3. Prosiding Seminar Nasional Teknologi Industri, Lingkungan dan Infrastruktur (SENTIKUIN), 3, 2020.
[25] H. S. Kusuma, U.O. Aigbe, K. E. Ukhurebor, R. B. Onyancha, B. Okundaye, I. Simbi, O. M. Ama, H. Darmokoesoemo, B. A. Widyaningrum, O. A., Osibote, V. A. Balogun. Biosorption of Methylene blue using clove leaves waste modified with sodium hydroxide. Results in Chemistry, 2023, 5, 100778
doi: 10.1016/j.rechem.2023.100778.
[26] I. Irdhawati, A. Andini, M. Arsa. Daya Serap Kulit Kacang Tanah Teraktivasi Asam Basa Dalam Menyerap Ion Fosfat Secara Bath Dengan Metode Bath. Jurnal Kimia Riset, 2016, 1(1), 52 - 57
[27] R. Zein, J. Satrio Purnomo, P. Ramadhani, Safni, M. F. Alif, and C. N. Putri. Enhancing sorption capacity of methylene blue dye using solid waste of lemongrass biosorbent by modification method. Arabian Journal of Chemistry, 2023, 16(2), 104480, doi: 10.1016/j.arabjc.2022.104480.
[28] A. B. Baunsele, E. G. Boelan, A. M. Kopon, R. Rahayu, and D. Siswanta. Kinetic Study of Blue Methylene Adsorption Using Coconut Husk Base Activated. Indo. J. Chem. Res., 2022, 10(2), 110–116,
doi: 10.30598//ijcr.2022.10-ans.
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doi: 10.1080/01932691.2016.1225263.
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Published
2024-05-31
How to Cite
MONIZ, Lucia et al.
OPTIMASI ADSORPSI METILEN BIRU MEMANFAATKAN SABUT BUAH LONTAR TERAKTIVASI ASAM.
CAKRA KIMIA (Indonesian E-Journal of Applied Chemistry), [S.l.], v. 12, n. 1, p. 17 - 31, may 2024.
ISSN 2302-7274.
Available at: <https://ojs.unud.ac.id/index.php/cakra/article/view/116361>. Date accessed: 13 nov. 2024.
Section
Articles
Petunjuk Penulisan
